Ch. 8 Periodic Classification Extra Questions
Q. Write 3 features of Mendeleev's periodic table.
A.・Elements are arranged according to their increasing atomic masses.
・There are 6 periods (horizontal rows) and 8 groups (vertical columns).
・Periods 4, 5 and 6 are divided into 2 halves.
Q. Which physical and chemical properties of the elements were used by Mendeleev in creating his periodic table? List two observations which posed a challenge to Mendeleev's periodic law.
A. Physical property used by Mendeleev was the atomic masses of elements and the chemical property used by him was the similar formulae of their oxides and hydrides.
2 challenging observations:
i) The position of isotopes: Isotopes are the atoms of same elements with different atomic masses and hence would be provided with different spaces in Mendeleev's periodic table.
ii) The position of hydrogen: Hydrogen resembles both alkali metals as well as halogens but it was placed with halogens in this table.
Q. How and why does the atomic size vary as you go:
i) from left to right across a period
ii) down a group
A. i)Atomic size decreases across a period as the number of shells remains the same but the nuclear charge increases due to increase in the number of protons. (Noble gases are an exception as they have bigger atomic size than halogens.)
ii) Atomic size increases down the group as the number of shells increases and the effective nuclear charge (ENC) decreases.
Q. How will the tendency to gain electrons change as we go from left to right across a period? Why?
A. The tendency to gain electrons i.e. electronegativity increases across a period as the number of electrons increases but the number of shells remains same.
Q. How does the electronic configuration of atoms change in a period with increase in atomic number?
A.In a period, as we go from left to right, the number of electrons (and the number of protons) increases as the atomic number increases but the number of shells remains same. Thus valency first increases and then decreases.
Q. Why was the system of classification into triads not found suitable?
A. Classification of elements was not found suitable because of the variations in the atomic masses observed and calculated. Moreover, only a few elements could be classified into triads.
Q. Elements have been arranged in the following sequence on the basis of their increasing atomic masses:
F, Na, Mg, Al, Si, P, S, Cl, Ar, K
i) Pick 2 sets of elements which have similar properties.
ii) The given sequence represents which law of classification of elements?
A. i) F and Cl, Na and Ar.
ii) The sequence represents Newland's law of octaves.
A.・Elements are arranged according to their increasing atomic masses.
・There are 6 periods (horizontal rows) and 8 groups (vertical columns).
・Periods 4, 5 and 6 are divided into 2 halves.
Q. Which physical and chemical properties of the elements were used by Mendeleev in creating his periodic table? List two observations which posed a challenge to Mendeleev's periodic law.
A. Physical property used by Mendeleev was the atomic masses of elements and the chemical property used by him was the similar formulae of their oxides and hydrides.
2 challenging observations:
i) The position of isotopes: Isotopes are the atoms of same elements with different atomic masses and hence would be provided with different spaces in Mendeleev's periodic table.
ii) The position of hydrogen: Hydrogen resembles both alkali metals as well as halogens but it was placed with halogens in this table.
Q. How and why does the atomic size vary as you go:
i) from left to right across a period
ii) down a group
A. i)Atomic size decreases across a period as the number of shells remains the same but the nuclear charge increases due to increase in the number of protons. (Noble gases are an exception as they have bigger atomic size than halogens.)
ii) Atomic size increases down the group as the number of shells increases and the effective nuclear charge (ENC) decreases.
Q. How will the tendency to gain electrons change as we go from left to right across a period? Why?
A. The tendency to gain electrons i.e. electronegativity increases across a period as the number of electrons increases but the number of shells remains same.
Q. How does the electronic configuration of atoms change in a period with increase in atomic number?
A.In a period, as we go from left to right, the number of electrons (and the number of protons) increases as the atomic number increases but the number of shells remains same. Thus valency first increases and then decreases.
Q. Why was the system of classification into triads not found suitable?
A. Classification of elements was not found suitable because of the variations in the atomic masses observed and calculated. Moreover, only a few elements could be classified into triads.
Q. Elements have been arranged in the following sequence on the basis of their increasing atomic masses:
F, Na, Mg, Al, Si, P, S, Cl, Ar, K
i) Pick 2 sets of elements which have similar properties.
ii) The given sequence represents which law of classification of elements?
A. i) F and Cl, Na and Ar.
ii) The sequence represents Newland's law of octaves.